I don't think she used every POV only once, but Anne Rice's The Mummy changes POV with every chapter.
If you're only going to use each POV once, you'd better decide now which POV will close the story -- it would almost have to be the character the reader most identifies with or roots for -- which presents a problem for you -- the reader will never see things from the MC's POV until the end.
How's this for an idea? Make the penultimate POV the villain's. That way, right at the end of the story, the reader gets to see things from the villain's POV, complete with whatever passions, grudges and/or rationalizations he goes through to justify his goals.
Then, next and last chapter, we finally see things from the hero's POV (maybe opening with the hero hanging onto a sheer cliff with his fingernails -- in any case, at his lowest point in the story).
Go for it, dude.
Well, there is no real villain and no real hero. It's just people, living in history.
Wait, is this me saying this? Am I REALLY writing a book with no Big Bad and Hero with flaming sword!
I MUST BE GOING MAD!
Ah well.
I've composed a list of characters I'm writing out here. I should really make a flow chart...but be sure you don't need it for reading.
PEACE MOVEMENT:
(Jul)ian: Bob Dylan, but less whiny and more politically interested. Dohina (half-elf)
Kayle: Extremist political activist on the edge of terrorisem. Slightly mad. Human.
(Mor)gan: The intelligent strong man. Simple, but book learned. Dohina.
Spencer: The nervous one. Wants to be part of a cause...but is this the one for him? Human.
Officer Karen Valerie: A peace officer on the other side of all those protests Julian and the others organize. Hard nose covers idealist inside.
Human.
22ND PLATOON:
L.t Harry: Gritty, hard nosed, "Kill the short-eared sons of bitches". Dohina
Wes: The FNG. Is gay but in denial. Elf.
Gal: Just doing his job. Need to think up more interesting character for. Elf
Fot: Joker, but so damn afraid on the inside. Elf.
(Other characters may appear here as I think them up)
THE CREW OF THE
FIST OF GOD:
Cpt. October: Really really hates her job. Human
1st Off. Helena: Pyromaniac. Human
2nd Off. Celena: Downright afraid of Helena. Human
GWENBLADE FAMILY:
Aria: Elven photographer, loving wife and mother of two. Elf.
Dad: Handless veteran. Good guy, in general. Elf
Lila: Annoyed daughter. Dohina, but don't tell her that.
Ris: Obnoxious son. Elf
ROYAL COURT:
Prince Kal: Scariest 12 year old you'll ever meet. Religious zealot. Elf
Regent: Old, nervous, and rather scared by Kal. Well, who isn't? Elf
Handmaiden Kes: Serving girl and tutor to Kal. Scared. Elf
Prof. Razp: Manipulative, self serving hoe. Not scared. Elf
1st L.T Twe: Gaurd. Scared. Elf.
PARLIAMENT:
Senator Traxton Hicks: Old guard. Conservative. Human.
Delilah: Secretary to Hicks. Human
Senator Josephine Brush: Old guard. Female. Human.
Senator Robert Elanor: New guard. Peace movement sympathizer. Human.
President Elysha Chidley: President of the Republic. Mostly powerless and frustrated by it. Human.
Secretary of War: Concerned with how the war is going. Wants to defend his homeland with every last breath in his body. Human.
CREW OF THE TP-55:
Tank commander: More detail later.
Front Gunner: More detail later.
Driver: More detail later.
HOMELESS:
Simon: Incredibly angry old man. Veteran of the Dragon War. Human.
The Dragon: A pitiful wreck, one of the last of a proud and beaten race. Dragon.
(other characters later.)
<Looks back up at list>
Oh god....
I've bitten off a lot.
<Sobs>