Yes, a slugline or scene heading indicates a new scene.
In a spec script, minislugs may be used for brevity if a scene has already been visited previously, e.g.
KITCHEN
but if the script sells then someone, probably at the prodco, will go through it and change the minislugs to full scene headings.
Writing your scenes headings on note cards gives you the option to move 'em around on the table or cork board so you can decide the best sequence of events. This can be done before writing the script, or during. Pro software programs like Movie Magic have a scene card view option, where you can click-and-drag scenes around as if they were actual cards, and the script will be re-ordered based on this action. You don't have to use cards (or software) but it's a useful planning tool.
-Derek