Coming at this question from another direction, what are the most likely causes of accidental fires, with no human intervention? Faulty electrical wiring or outlets would be one, I'd think. My sister-in-law's house caught fire a few years ago owing to a faulty construction of a fireplace flue.* Lightning, maybe, but then you'd pretty much know from the weather itself. A gas or fuel leak of some kind, undetected. But these kinds of fires generally leave indications of the place of origin. Another possibility, human caused but quite possibly delayed for some time, would be smoking materials left smoldering in a bed or sofa or chair.
Fires lacking in characteristics that fit those scenarios are automatically considered suspicious, I would think. Accelerants leave traces, nearly always, which can be detected by competent fire investigators. But scientific investigations do take time. We scientists are slow, careful bastards.
And, for a detective, motivation of possible suspects is a significant issue, too.
caw
* The fire smoldered unnoticed for several hours before fully breaking out in the middle of a cold December night. I happened to be visiting over the Christmas holidays, and staying at my father-in-law's house just a block away, and it happens that he was a retired fire chief for the town, and had a working police/fire radio monitor, so we knew about it as soon as the call was placed. Fortunately, everyone got out, and they were able to keep the house from being a total loss, although there was a lot of damage.