Thanks for the help guys. I may have the hostage taker be an idiot and assemble the gun wrong after he cleaned it... then it falls apart in his hands. It'll be funnier that way and still use the parts hitting the floor.
This is already pretty funny. You could have the idiot gunman know zip about guns and get advice about gun handling from the hostages.
However, if your object is to have a gun part clatter to the floor, then it's correct that a revolver isn't the best for parts dropping off.
Also, the slick and instant removal of the slide-release pin by Mel Gibson or Steven Seagal is pretty much movie FX hype.
Yet with idiocy a factor, here's a scenario to consider:
The gunman has a Model 1911 or similar knockoff. The pistol is just a threat, so he inserts an empty magazine ("clip" is a good misnomer for someone who doesn't know guns) just for dramatic show to intimidate the hostages.
However, when he racks back the slide to fake loading for the hostages, the slide locks back (as it should, because the magazine is unloaded). When he goes to thumb the slide-release to let the slide go forward to continue his bluff, he accidently thumbs the magazine-release button, and the empty magazine drops free and clatters to the floor.
I tried it , it works, and I'm still giggling while writing this.